![]() The site offers almost every kind of torrent in high-quality. RARBG started as a Bulgarian tracker, but due to immense popularity and fan following, it changed into a torrenting website. The site offers all the latest movies, however, it also informs users to use a VPN before streaming due to IP leaks that can give your ISP or government access to your online traffic. The best part of streaming on YTS is that it offers movies in the smallest file sizes for you to download easily, even with an average internet speed. The site offers users to live to stream their favorite movies and shows in full HD (720, 1080p) and 3D quality. YTS.ag is a newer version of YTS.am which was shut down after facing copyright issues, but it’s back now and better than ever. ![]() Other than the usual movies and TV shows that everyone else is offering, KickAss Torrents has a database of torrents with software, books, games, music, and much more! The interface is something that might be disapproved by some users but on the whole, it makes for a great Pirate Bay substitute. It is super easy to use and has everything that the Millennials these days want. The largest BitTorrent system is KickAss Torrents. The Best Pirate Bay Alternatives That Work Right Now 1. To help you find the best alternatives to Pirate bay, here is a detailed view of each of the best Pirate bay proxy we have on our list. Why You Should Find Pirate Bay Alternatives?Īlthough not many torrent websites come close to the variety and availability of torrents provided by The Pirate Bay, since it is not working anymore, it is necessary for everyone to look for other alternatives. Consequently, The Pirate Bay started to suffer significant downtimes and legal authorities in several countries imposed a ban on the website. The website’s founder was also arrested on charges of computer hacking. Since 2007, The Pirate Bay has suffered from various legal issues. It was the best torrent site due to its user-friendliness, safe experience, and huge variety of available torrents. However, it drastically grew and became the most-visited torrent site. Initially, The Pirate Bay was just a crowdfunding platform hosted on four Linux servers. Get FastestVPN Why The Pirate Bay Is the Best for Torrenting? To bypass ISP blocks, you need a Fastest VPNfor torrenting to be able to access all of the above torrenting sites and then download your favorite torrents. Note: You may not be able to access the torrenting sites listed above in your region due to ISP blocks. We decided to make a list of the best Pirate Bay alternatives that you can access to download your favorite content in case The Pirate Bay website ever goes down. At times it is due to technical issues, while other times it is due to legal matters. Like other torrenting websites, the site frequently goes down. ![]() However, the site has been at the receiving end of extreme online lawsuits. It features a user-friendly interface and has an active community for its users to interact. It offers millions of torrent files of all genres. The Pirate Bay is one of the biggest and the most popular torrenting websites in the world. ![]() PirateBay: Best Pirate Bay Alternatives For Fast and Anonymous AccessĪugBy Christine Margret 1 Comment 11 minutes
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![]() I have one of you s.o.b.s to blame for talking about the show. I've seen it more than once, and in dry CA, too. I have been majorly binging Vice Grip Garage. We'll see if Derek runs into that.there's a good chance he will. One issue I've seen with these Pontiacs that sit more than 20 years, is the timing covers dissolve around the water pump plates internally from electrolysis, and you can't tell anything is wrong but the thing will get HOT. Every vehicle has a history waiting to be told. That said, the 335HP, AC/Auto equipped VG Garage goat likely has 2.93's out back so it would be a lot more leisurely getting to 60! A small Minnesota & Wisconsin family based Garage thats wrenching like the everyday guys and gals. ![]() ![]() Bieri calls spark plugs sparkolators, carburetors are. Motortrend ran a test with a 4 speed car and an auto car in 1967 and did 0-60 in 4.9 seconds with M&H street/strip tires on the back and a set of 3.90 gears. Derek Bieri, the host of the popular YouTube channel Vice Grip Garage, describes his car-related. His claim of 0-60mph in 5.2 seconds is, shall we say, optimistic. I'm sure Derek will get it all sorted out, and I'm looking forward to the future episodes. This past year has been a big one for Vice Grip Garage. XP103 Line: ATO 4.5 (8) Check Vehicle Fit Select a store to see pricing & availability or search by City & State or Zip: Find Limited Lifetime Warranty Seat: Tapered Thread Size: M14 Hex Size (mm): 16mm Compare Autolite Iridium XP Spark Plug - XP104 Part : XP104 Line: ATO 4. Second, the new location will be closer to major highways, making it more convenient for customers. ![]() First, the current location isn’t large enough to accommodate the business’ growth. But, Im curious on his galding spark plug problem. It sounded at times like there was some bearing noise coming from one of the engine accessories (water pump would be my guess). Vice Grip Garage Sparkalator Part 1776 Line: VGG This item is not available for purchase. Decemby Eric Devin The reason for Vice Grip Garage’s move is two-fold. Looks like a very solid and complete car that hasn't been monkeyed with. I enjoy Vise Grip Garage and watched this episode when it premiered on Friday. ![]() ![]() ![]() The 11th annual San Diego Fringe Festival continues with a promise to bring “the beautiful, the bizarre and the unexpected” to fans. The fest concludes Saturday with the sold-out Awards Celebration. Screenings cost $10 with discounts for service members and vets. There’s one more chance to catch the GI Film Festival San Diego – check out three slates of short films Friday evening at the Museum of Photographic Arts in Balboa Park. ![]() So, let’s enjoy this San Diego weekend while also counting down to the long weekend JUST ahead. Unofficial summer, of course, starts with Memorial Day. Photo by Chris Stoneĭo you feel the anticipation? If May Grey tells us anything, it’s that summer is right around the corner. Alas Brandon wasn't on shift, but the food was fine, service attentive, and the big screens tuned to our request.Kids of all ages can enjoy the kites, big and small, at the OB Kite Festival. We ended up going back Sunday night for dinner. And now we want to tell the Trip Advisor world! well, we were starving but we came out of there stuffed.īrandon was our server, and he was so engaging and helpful that we had to tell the GM. The Teriyaki sliders - FOUR OF 'EM! - were delicious, and the Jungle Caesar. We were going to get the Beachside sliders, but our thoughtful server said we should hold on because the portions were going to generous.Ĭheese fries were enormous and yummy - crisp with a soft, flavorful blanket of cheese and chopped scallions. Next we went on with another mojito and food - the Teriyaki sliders, the cheese fries and the Caesar with chicken. He started with the mojito, I kicked off with a so-so margarita. We arrived at the beginning of happy hour, having just gotten off the plane and hoping to crush our thirst and appetites. If you frequent Islands but have not been to this one you should go! No doubt we will be back!!!! More If you are in the area this place is well worth the stop. We had dinner and a couple of drinks, the food was excellent as was the service given by the employees. The restaurant was pretty busy but our orders were brought to us in a very reasonable time and as expected were very good! I did notice that soon as a table was vacated by diners the staff cleaned it immediately! The server took our drink orders quickly and then our dinner selections. safety precaution I am sure, and appreciate the effort! The dining area and bar area both seemed like they were cleaned frequently. The table had already been bussed and cleaned prior to our arrival, it was again sprayed down and cleaned as we were seated. There was a good crowd inside but there were open tables and we were seated immediately. The parking lot, and exterior grounds of the building were both clean and well maintained. ![]() This location is in a large shopping mall with plenty of parking available. This was an unexpected stop and yielded the high quality experience we have come to expect! We have eaten at other Islands locations but had never stopped here. Mission Valley / Hotel Circle Restaurants. ![]() Families with children Restaurants in Mission Valley / Hotel Circle.American Restaurants for Lunch in Old Town.Restaurants with Outdoor Seating in San Diego.Restaurants for Special Occasions in San Diego.Restaurants for Group Dining in San Diego.Mediterranean Restaurants for Large Groups in San Diego.French Restaurants for Special Occasions in San Diego.Hotels near (SAN) San Diego Intl Airport.Hotels near Torrey Pines State Natural Reserve.Hotels near Old Town San Diego State Historic Park.Hotels with Military Discounts in San Diego.Extended Stay America Hotels in San Diego.Four Points by Sheraton Hotels in San Diego.Preferred Hotels & Resorts in San Diego. ![]() ![]() Magneto is considered one of the best cruiser board brands due to its thoughtful products. As for its size, it has a 27.5-inch long and 7.5-inch-wide body. If you are looking for a wooden mini cruiser skateboard instead of a plastic one, try Magneto Mini Cruiser Short Board. Magneto Wooden Mini Cruiser Skateboard With Double Kicktails Therefore, you will be able to jump right into skating just by unwrapping the package.Ģ. When you open the skateboard package, you will find a complete board with a thank you card. All of these boards feature exotic colors and elegant patterns, making them hard to dislike. This example of short cruiser skateboards comes in multiple color choices to accommodate different people’s tastes. As a result, you can just hold it in your hands to carry it around with you when you need to. The mini cruiser has a 22-inch length with a 6-inch width, weighing only 3.79 pounds. What makes it stand out even more amongst the cool cruiser skateboards in the market is its easy-to-carry build. According to the safety experts, the short cruiser skateboard has a bendable and sturdy Polypropylene deck that is unlikely to break at a sudden notice. ![]() The proof is its CE safety certification. But despite being made of plastic and possessing a delicate-looking build, Meketec Mini Cruiser is anything but that. Many deem plastic skates unsafe due to their thin, flimsy outlook. These qualities make it one of the most liked beginner cruiser board options in the market. ![]() Therefore, the board has a superior balance and can absorb road impacts better than most shortboards. These wheels have a 78A hardness level and are 60*45mm in diameters. Underneath its durable, high-quality 3.25-inch heavy-duty aluminum trucks, there are four polyurethane wheels attached. In addition, its medium-sized gives it such a cute look!ĭespite its smaller size, it has the quickest movement capacities. This plastic-made best skateboard for cruising is designed to offer you the best skating experience you can get from a penny board. Meketec Complete Mini Cruiser 22 Inch Skateboardĭo you want a mini-cruiser with the best stroll capacity? Meketec Mini Cruiser Retro Skateboard is here at your service. We have selected six of the best cruiser skateboards for you and reviewed them unbiasedly.ġ. You may not have the patience and time for tiresome and lengthy researches. Although the market is full of options, only a few are of top quality. While buying yourcruiser skateboard, you need to pay close attention to its quality and build. Their build makes them highly suitable for commuting, but not so much for performing tricks.īest Cruiser Skateboards: Top 7 Selections & Reviews The primary distinguishing points between them are that the cruisers have comparatively softer wheels with bigger radius and flexible trucks. ![]()
![]() We follow a number of recent authors, who have considered additional contributions to the gravitational potential in the form of Yukawa-like terms ( White & Kochanek 2001 Peebles 2002 Sealfon et al. In the present paper, we will concentrate on this last aspect. Finally, large galaxy surveys have been analysed looking for signatures in the power spectrum due to deviations from the inverse-square law ( Sealfon, Verde & Jimenez 2005 Shirata et al. Recently, proposals have been made to extend these theories to a general covariant framework ( Bekenstein 2004) and evolution of perturbations in this theory has been considered ( Skordis et al. The implications of MOND on large-scale structure in a Friedmann–Lemaître–Robertson–Walker (FLRW) universe were discussed in Nusser (2002). Constraints on Newton's constant from the primordial abundances of light elements were discussed by Umezu, Kiyotomo & Masanobu (2005). Such radical modifications of gravitational physics may seem difficult to test, but our ability to make precise observations of cosmological dynamics on scales of ≳10 h −1 Mpc is now good enough to permit detailed tests of gravity theories even on these scales.Įxamples of such work include White & Kochanek (2001), who determined constraints on the long-range properties of gravity from weak gravitational lensing cosmic shear. On one hand, MOND proposals make gravity stronger on scales of galaxies to explain flat rotation curves without dark matter ( Milgrom 1983 Sanders 1998), on the other hand, alternative theories aim to find a mechanism for cosmic acceleration without dark energy, as a result of gravity leaking into higher dimensions on scales comparable to the horizon ( Dvali, Gabadadze & Porrati 2000). The body of evidence is quite impressive, considering the enormous extrapolation from the empirical basis, but the gravitational inverse-square law and its relativistic generalization are supported by high-precision tests from measurements in the laboratory, the Solar system and the binary pulsar only up to scales of ≲10 13 cm ( Aldelberger, Heckel & Nelson 2003).ĭespite the overall success of general relativity, non-standard theories have received much recent attention, largely motivated by finding alternative explanations for the ‘dark’ sector of the Universe. General relativity has passed many important tests up to the length- and time-scales of the observable Universe ( Peebles 2002, 2004). Gravitation, cosmology: theory, dark matter, large-scale structure of Universe 1 INTRODUCTION Back-reaction on density growth from a modified cosmic expansion rate should, however, also affect the normalization of the power spectrum, with a shape distortion similar to the case of a non-modified background. ![]() This phenomenon is almost perfectly degenerate in power-spectrum shape with the effect of a background of massive neutrinos. Enhancement of gravity affects the subsequent evolution, boosting large-scale power in a way that resembles the effect of a lower matter density. ![]() The coupling between baryons and cold dark matter across recombination is negligibly affected by modified gravity physics if the proper cut-off length of the long-range Yukawa-like force is ≳10 h −1 Mpc. Evolution of perturbations is considered in general non-flat cosmological models with a cosmological constant, and an analytical approximation for the growth function is provided. ![]() We model such deviations as a Yukawa-like contribution to the gravitational potential and discuss the growth function in a mixed dark matter model with adiabatic initial conditions. Deviations from the gravitational inverse-square law would imprint scale-dependent features on the power spectrum of mass density fluctuations. ![]() ![]() ![]() It’s very widely used in marketing, most obviously in the giving of free gifts or samples. When people are given something, even if they didn’t ask for it, they feel strongly compelled to give something back in return. As long as there is no trick or deception involved, all parties should get what they want. What’s all this got to do with selling online? Well, buyer psychology is human psychology, and sellers can create the conditions to encourage a normal social response. If for some reason we act against a norm – either actively or by doing nothing – it feels unpleasant, uncomfortable, even stressful. Like the animals, when presented with the right scenario, we respond immediately with a set behavior – a behavior programmed into our genes and reinforced by learning over thousands of years. We don’t need to stop and consider if there is a norm at play, we just act. So social norms are extremely powerful, and largely automatic. Failure to reciprocate could quite literally lead to starvation. But if you break the norm, and refuse to share, when you are hungry they will feel less obliged to share back. For example, sharing food with a hungry neighbor would compel them to share back when they have more than you – the norm of reciprocation. When humans depended on their tribes for survival, good social practices could mean the difference between life and death. The ultimate consequences of breaking social norms can be quite severe. If you don’t follow them, you won’t be breaking any laws (on the whole) but your standing and acceptance in society could suffer. Social norms are the “rules” that say what society expects of us. Humans don’t have those kind of truly instinctive behaviors, but we do have something similar – the social norms that we all follow. These behaviors are completely dependable: given the right trigger (or even a rough approximation of it) they always play out in exactly the same way. The WeaponsĮverywhere in the animal world there are instinctive responses – set sequences of behavior that occur in response to a specific trigger, such as birds’ mating dances. Much (but not all) of the potential to influence marketplace buyers lies with the marketplace itself, as they “own” the relationship with the buyer. But there is an important practical difference: there are fewer opportunities to influence marketplace buyers than direct buyers. Just a note: all this is relevant – in theory – whether you sell on marketplaces or through an independent store. Established sellers have more to play with, and might get a better return on their efforts by working on order value or customer loyalty. If you aren’t getting any orders, it’s a big jump to getting larger orders or multiple orders. Get buyers to buy again – measured by customer lifetime value (CLV).īroadly speaking, new sellers should concentrate on “converting” visitors into buyers before anything else.Get buyers to buy more – measured by average order value (AOV).Get buyers to buy – measured by conversion rate.Each can be measured and analyzed separately: There are three objectives that online retailers typically focus on. Influencing buyers sounds great, doesn’t it? But what do we want to influence them to do? That may sound like a naive question, but the answer is actually more nuanced than simply “to buy stuff”. Although it’s a little sensational, it does capture the brute power they hold. The term “weapons of influence” is Cialdini’s, not mine, by the way. So there’s your social proof! (Don’t worry – if you don’t get that now, you will later!) It has itself been profoundly influential on marketing in every industry and every part of the world.Ĭialdini’s book has sold 2 million copies and been translated into twenty-six languages. It sounds like hype, but this is no new marketing fad – Influence is a classic business book from thirty years ago. In his book Influence: The Psychology of Persuasion, Robert Cialdini describes how six behaviours are used in marketing, to remarkable effect (it’s on and .uk). You can use them to be a much more effective seller. In this post, I set out the six behaviors hard-wired into our brains – actually programmed by evolution – that are immensely influential in buyer psychology. We are anything but rational in many aspects of our lives, and shopping is no different. But the majority of buyers don’t buy that way – even though they may believe they do. ![]() Do they carefully define all their requirements, search for a seller and product that ticks all the boxes, then make a purchase? ![]() ![]() ![]() Evelyn, however, finds out that a creature has found its way into the basement. Marcus is instructed by Lee to light some fireworks as a distraction, and he uses this chance to save Evelyn and puts her in the basement, before going out to look for the other children. This attracts a creature, but Evelyn manages to warn Lee and Marcus by turning on the red lights outside the house. In the meanwhile, Evelyn goes into labor and while heading to the soundproof basement, she steps on a nail and the jolt of pain causes her to knock down a picture, causing noise. Lee tries to save him, but the old man willingly screams and invites death. Their trip back home is eventful as they meet an old man whose wife has been killed by one of the creatures. Marcus, meanwhile, has a heart to heart chat with his dad, telling him that he should reach out to Regan and assuage her guilt. He explains that the creatures are drawn to the loudest sound, so in the presence of louder sounds, they are safe. We see some quality father-son bonding time, as Lee takes Marcus fishing. Lee tries to help Regan’s hearing with a new implant, but it does not seem to work. The story moves forth a year, with Regan blaming herself for Beau’s death and Evelyn pregnant with another child. ![]() The four-year-old Beau activates the toy while crossing a bridge, attracting one of the creatures, who kills him. But Regan gives the toy and the batteries to her brother, not knowing any better. Beau is drawn to a battery operated toy that Lee rejects since it would make noise. They scavenge for supplies and use the American Sign Language or ASL to communicate in the open so as not to make noise. We are introduced to the Abbott family, with husband and wife, Lee and Evelyn, Regan, the deaf daughter, and two sons Marcus and Beau. This causes them to attack anything that makes noise, and the species of the earth are defenseless against their indestructible armored skin. These creatures appeared from a meteor shower and though they are blind, they have a heightened sense of sound. ‘A Quiet Place’ starts in the year 2020, and is a post-apocalyptic tale where most of the world’s population has been wiped out by extraterrestrial creatures. ![]() However, before we get into where you can watch ‘A Quiet Place’, let us quickly tell you what it is about. This is the perfect time to acquaint yourself with the movie if you have not seen it, or to relive this gripping tale if you have watched it already. A sequel is slated for release on March 20, 2020. Eschewing the normal sounds it requires to make the jump scares and horror elements effective, the film goes in another direction, using oppressive silence to create an all-engulfing atmosphere of horror. 2018 indeed was a great year for John Krasinski, who directed and starred in this movie, besides also beginning to play the part of Jack Ryan in Amazon Prime’s show.Īnyway, coming back to ‘A Quiet Place’, the film has been described as “smart, wickedly frightening good time”. The movie has been praised for the atmosphere of dread that it manages to create, not to mention the acting, direction and sound design. ![]() ![]() ![]() This handy RV tool is on Tony’s wish list! An infrared thermometer gun reads your tire temperature with the click of a button! Our full-time RV friends had this while we were caravaning across Michigan, and it was so cool (no pun intended) to see the quick results! After being on the road full-time for over 1 year, we finally bought our screen porch tent and it was the BEST purchase we made that year. We LOVE our super easy-to-set-up pop-up Gazelle screened-in porch gazebo and recommend it to anyone who stops by. I’d recommend grabbing a carrying case for your Blackstone too.Ĭheck out the tailgating Blackstone combination at Campingworld here. ![]() Convenient, portable, and so easy to clean, this is a great RV accessory! We have many RV friends that use theirs almost daily. This Blackstone grill is an awesome addition to your RV camping list. Or, if you’re looking for a list of things you do NOT need for your RV then check out this post.īut hey, the fun camper accessories are totally worth checking out, right? 1. If you’re looking for the RV accessories that you really might need, then check out our ultimate post of RV must haves here. The items that could add to your enjoyment, but they may not always be a must have RV item. These items are fun RV accessories that would make great camping gifts for Christmas, birthdays, or maybe a send-off to a new RV road trip adventure! They are cool camping gadgets that would make great gifts for RV owners of all kinds, and also cool RV gadgets for yourself.įirst, I do need to point out that these are the FUN things. Recently updated list! Fun RV Accessories PLEASE READ OUR DISCLAIMER FOR MORE INFO. THIS ARTICLE MAY CONTAIN COMPENSATED LINKS. Then check out our list of fun RV accessories that our family either has now, or wants to have. Or, are you looking to become a full-time RV living family and want to know what the ‘cool RV stuff’ really is? The load capacity of your unit is designated by weight, not by volume, so you cannot necessarily use all available space when loading your unit.Are you looking for a list of fun RV accessories that might inspire you to pick up the latest camper gadgets for your RV? A list of RV gifts for RV owners or unique RV accessories that you haven’t heard of yet? A label identifying the unloaded vehicle weight of the actual unit and the cargo carrying capacity is applied to every Forest River RV prior to leaving our facilities. ![]() **Estimated Average based on standard build optional equipment.Įach Forest River RV is weighed at the manufacturing facility prior to shipping. Available CCC should accommodate fresh potable water (8.3 lbs per gallon).īefore filling the fresh water tank, empty the black and gray tanks to provide for more cargo capacity. *Estimated Average based on standard build optional equipment.ĬCC (Cargo Carrying Capacity)** - is the amount of weight available for fresh potable water, cargo, additional optional equipment and accessories.ĬCC is equal to GVWR minus UVW. The UVW does not include cargo, fresh potable water, additional optional equipment or dealer installed accessories. It includes all weight at the unit’s axle(s) and tongue or pin and LP Gas. UVW (Unloaded Vehicle Weight)*- is the typical weight of the unit as manufactured at the factory. GAWR (Gross Axle Weight Rating) – is the maximum permissible weight, including cargo, fluids, optional equipment and accessories that can be safely supported by a combination of all axles. ![]() ![]() Marissa says: “Very tender and really good”. the dip is delicious”. Bob agrees: “The Boneless Rib Eye is so flavorful and tender”. Just like when I ate at Paul Bocuse in France, I must once again steal concepts! lol I had not thought to do that, and that’s what makes Top Chef Richard Blais, Richard Blais. ![]() If you think about it, it’s sweet and savory just like Marissa says, which always works. but I have never even thought to stuff a date with a regular protein. And as people start commenting about them, everyone at the table joins in, saying they enjoy them.Īs a chef I can tell you I create blue cheese stuffed dates…. It has a good sweet and savory blend to it”. Marissa says: “I really enjoy the Stuffed Dates. We then move on to Sausage Stuffed Dates and pigs in a blanket rye mustard. who is always there to snap those beautiful pix! The pix you do have here are mine and from Bob K. Wish I had a picture but those went pretty quickly too. Wow! That’s a pretty good recommendation I’d say! And that’s just an appetizer choice from their snack bar. What does that conjure up for you? Well one of our eaters, Diane says: “That’s the best thing I have had in years. First let me mention: White Chocolate Dipped Radishes. I will really thrilled with how Richard Blais names everything he serves and lives up to my personal expectation of good food. ![]() If you check out the table, you will see lots of happy faces. It’s a show in itself, when they pull the top off as the smoke drifts out. But I’m not going to let another day go by, before knocking this review out, because it is a restaurant worth reviewing. ![]() You can imagine that between the blog, the restaurant reviews and all the new events I create every two months, it sometimes gets away from me. Although I went there weeks ago, it has been 9 Chef Marian Foodies Ember & Rye Restaurant Review Todays’ Restaurant Review is Ember & Rye, Carlsbad. ![]() ![]() But is there a way to compare these guys? So is there a way to say Okay, which one is Maura Unsaturated In which one is less unsaturated because they're both very different. So we know that we can use the words saturated and unsaturated to describe this. So what I'm trying to say is that a ring actually takes some hydrogen away from the carbon structure. So that means that now you have to make them ch two. When you make a ring, they have to fuse together. Because what that means is that the end that one of the end is supposed to be ch three on the other end is supposed to be ch three. Rings are also going to take away some of the hydrogen for a molecule. They both have pi bonds and then also rings. Remember that pie bonds just have to do with double bonds or triple bonds. OK, Johnny What makes carbons, Miss Hydrogen? Why would you be missing some? It turns out it only happens for two different reasons. And unsaturated fat would be one that's missing a few hydrants. Are these long carbon chains? There would be this fat that has many hydrogen as possible. So saturated fat would actually be a fat fats. ![]() And that's because these are words we use actually within cooking. And these air words saturated and unsaturated, they might sound familiar to you. ![]() Okay, any molecule that has less than that number to M plus two is gonna be considered to be unsaturated. I need for my structure, for it to be fully saturated, meaning it has many hydrogen, as it can possibly hold. Okay, so I have my two in plus two rule, and what that's gonna do is it's gonna predict for me how maney hydrogen is. It's to end plus two where N is equal to the number of carbons. And that formula is maybe remember it from Gen. ![]() And there's this formula that we can use in all chemistry to figure out if it has many hydrogen is possible. Well, what it has to do with is how unsaturated or saturated a molecule is So what's that word saturated? Well, a saturated molecule is any molecule that has many hydrogen as possible. So first of all, let's just talk about what is index of hydrogen deficiency. What I'm gonna do on this page is to show you the structural one, which is actually the easier one, and then we'll move on to molecular formula. And that is one structural, and the other one is with molecular formula. So there's actually two different ways to compete, to compute the H d. So what I'm gonna do here is gonna jump a little bit forward and teach you something that you don't need to know yet because it's gonna make isom are so much easier to understand for this chapter. So you're probably thinking, Johnny, why are you teaching this to me? If I don't need to know it yet Well, because there's this other topic called Constitutional I Summers and that topic is much easier to understand if you already know the HD rules. And this is a topic that usually isn't covered in the first chapter of most textbooks. And I'm going to talk about a topic called Index of Hydrogen Deficiency. ![]() |